Is there a way to watch Anime Network on my TV? with out it being on demand. I have the Anime Network Free on the tv but how do i get the movies on this site on there or is it only on computer?

Anime Network Online is for computers. Your best option is to get a LCD TV (or similar) and connect your computer and cable box to that.

Otherwise no, they are two different services and infrastructure networks: VOD is operated by your cable or satellite provider while Anime Network Online is operated by Anime Network.